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A novel method for stereoselective synthesis of β-trifluoromethylated homoallylic alcohols in water

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
38
Issue
5
Identifiers
DOI: 10.1016/s0040-4039(96)02434-3

Abstract

Abstract The indium-mediated allylation reaction of aldehydes with 1,1,1-trifluoro-4-bromo-2-butene in water afforded an important trifluoromethylated building block β-trifluoromethylated homoallylic alcohol with high yield and excellent diastereoselectivity.

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