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Synthesis, spectroscopic investigations, antimicrobial and DNA binding studies of a new charge transfer complex of o-phenylenediamine with 3,5-dinitrosalicylic acid

Authors
Publisher
Elsevier B.V.
Volume
102
Identifiers
DOI: 10.1016/j.saa.2012.10.027
Keywords
  • O-Phenylenediamine
  • 3
  • 5-Dinitrosalicylic Acid
  • Charge Transfer
  • 1H Nmr
  • 13C Nmr
  • Dna-Binding

Abstract

Abstract A charge transfer complex of o-phenylenediamine (OPD) as donor with 3,5-dinitrosalicylic acid (DNSH) as acceptor, was synthesized and characterized by FTIR, 1H NMR, 13C NMR, mass spectroscopy, elemental analysis and X-ray crystallography. The structural investigations exhibit that the cation and anion are joined together by strong N+H⋯O− type hydrogen bonds and stoichiometry of CT complex was found to be 1:1. The CT (charge transfer) complex shows remarkable interaction with Calf thymus DNA, and the CT complex was also screened for its microbial activity such as antimicrobial and antifungal activities. A molecular frame work through H-bonding interactions via n→π* transitions between neighboring moieties is found which is responsible for high melting point of resulting CT complex. This has been attributed to the formation of 1:1 CT complex.

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