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A comparative He(I)/He(II) study of the photoelectron spectrum of benzoyl chloride

Authors
Journal
Journal of Electron Spectroscopy and Related Phenomena
0368-2048
Publisher
Elsevier
Publication Date
Volume
15
Issue
1
Identifiers
DOI: 10.1016/0368-2048(79)87013-9

Abstract

Abstract The He(I) and He(II) photoelectron spectra of benzoyl chloride have been subjected to a relative band intensity analysis. The spectral assignment, which is supported by theoretical ionization cross-sections calculated from a GAUSSIAN 70 wavefunction, illustrates the use of He(II) radiation for molecules containing heavy atoms. The low ionization potentials of benzoyl chloride are described in molecular orbital terms as π < π < n o < n Cℓ ∼ n Cl.

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