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Chemical trend of Mn 3d states in MnY (Y  S, Se, Te)

Authors
Journal
Physica B Condensed Matter
0921-4526
Publisher
Elsevier
Publication Date
Identifiers
DOI: 10.1016/s0921-4526(97)00090-2
Keywords
  • Chapter 8. Chalcogenides And Pnictides
Disciplines
  • Chemistry

Abstract

Abstract Mn 3d states in MnY (Y  S, Se, Te) have been investigated by resonant photoemission experiments in the Mn 3p-3d excitation region. For all compounds, a characteristic feature with three structures at 0–2.5 and 3.5 eV, and around 8 eV below the valence-band maximum is observed. A chemical trend of the Mn 3d DOS's in MnY is interpreted by the increases of a ligand to 3d charge transfer energy and/or p-d hybridization from MnTe to MnS.

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