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Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys

Wiley - V C H Verlag GmbH & Co. KGaA
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Alloy, alloy: A pure cobalt-based Keggin network linked by W-O-Co interactions is “alloyed” with a pure manganese-based Keggin network, linked by W-O-Mn interactions. These isostructural alloys are solid solutions of the Co and Mn nets. The alloys are prepared by the stoichiometric mixing of the components of each discrete network, leading to a series of single-crystalline mixed transition-metal frameworks with novel redox properties.

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