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Vibrational spectra of cis- and trans-1,2-dimethyl-3-bromocyclopropane

Authors
Journal
Spectrochimica Acta Part A Molecular Spectroscopy
0584-8539
Publisher
Elsevier
Publication Date
Volume
39
Issue
6
Identifiers
DOI: 10.1016/0584-8539(83)80098-1
Disciplines
  • Physics

Abstract

Abstract The infrared and Raman spectra of cis- and trans-dimethylbromocyclopropane have been recorded from 4000 to 50 cm −1. An assignment of the majority of the fundamentals is proposed and compared to those of related molecules. Definite and consistent trends in a number of normal modes of the ring and the methyl groups with the nature, position and number of the substituents have been found. Clear evidence has been obtained for steric interaction between the three substituents in cis-position.

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