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XPS and BIS spectra of U3T3X4(T=Ni, Cu and X=Sn, Sb)

Authors
Journal
Physica B Condensed Matter
0921-4526
Publisher
Elsevier
Publication Date
Identifiers
DOI: 10.1016/0921-4526(93)90502-w

Abstract

Abstract Valence state and U 4f core spectra of ternary uranium compounds U 3T 3X 4(T=Ni, Cu and X=Sn, Sb) are measured by X-ray photoemission and bremsstrahlung isochromat spectroscopy. The diffreences in the spectral shapes of valence bands suggest the importance of the hybridization of U 5f states with T 3d and X 5p states. For all compounds, the unoccupied U 5f state spectra are similar in shape except for small differences in the tailings.

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