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Thermodynamics of Iodine under High Pressure at Low Temperatures

Elsevier B.V.
Publication Date
  • Physical Chemistry > Theoretical Chemistry
  • Physchem/0305005


The Clapeyron equation was applied to phase diagram of iodine at low temperatures. It has been shown that it fails to describe it. A modified Clapeyron equation has been offered which gives much better results. It is supposed that the transition from the low pressure phase to the high pressure phase happens like this: molecular phase - molecular phase with a body-centered orthorombic Bravais lattice - monatomic phase with a body-centered orthorombic Bravais lattice.

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