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Magnetic circular dichroism of group via hexacarbonyls

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
73
Issue
3
Identifiers
DOI: 10.1016/0009-2614(80)80715-9

Abstract

Abstract The magnetic circular dichroism spectra of Cr(CO) 6, Mo(CO) 6 and W(CO) 6 have been measured. The A terms for the two low-lying charge-transfer transitions in these compounds were calculated using the irreducible tensor method. For the second CT transition an alternative assignment is proposed contrary to the one hitherto assumed.

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