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C-C and C-N coupling reactions of an imidotitanium complex with isocyanides

Authors
Publisher
American Chemical Society
Publication Date
Keywords
  • F100 Chemistry

Abstract

Reaction of the imidotitanium complex (k3-N2Npy)Ti(=NtBu)(py) (1) N2Npy = (2-C5H4N)C(Me)(CH2NSiMe3) 2 with 2,6-xylylisocyanide led to double insertion of the isocyanide into the imidotitanium bond and yielded the four-membered titanacycle (k3-N2Npy)Ti-{N(tBu)C(=N-2,6-Me2C 6H3)C(=N-2,6-C6H3Me2)} (2), which was characterized by X-ray crystallography. © 2000 American Chemical Society.

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