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Some coordination compounds of zirconium tetrabenzyl and some reactions in which there is insertion into carbonzirconium bonds

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
74
Issue
3
Identifiers
DOI: 10.1016/s0022-328x(00)83686-4

Abstract

Abstract Zirconium tetrabenzyl (ZrBz 4) has been allowed to react with a number of nitrogen and oxygen donor ligands. Air-sensitive complexes of formula ZrBz 4·2L ZrBz 4·L or 2ZrBz 4·L have been isolated and characterised by analysis and by NMR and IR spectroscopy. The reaction of ZrBz 4 with SO 2, PhNCO and MeNCS gave ZrBz(SO 2Bz) 3, Zr[NPhC(O)Bz] 4 and Zr(NMeC(S)Bz) 4 respectively.

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