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Clathrate and inclusion compounds—II (1). The Raman spectra of Hofmann-type benzene and benzene-D6clathrates

Authors
Journal
Spectrochimica Acta Part A Molecular Spectroscopy
0584-8539
Publisher
Elsevier
Publication Date
Volume
30
Issue
6
Identifiers
DOI: 10.1016/0584-8539(74)80100-5

Abstract

Abstract The Raman spectra of powdered, crystalline samples of the Hofmann-type benzene clathrates, Ni(NH 3) 2Ni(CN) 4.2C 6H 6, Ni(NH 3) 2Ni(CN) 4.2C 6D 6, Cd(NH 3) 2Ni(CN) 4.2C 6H 6 and Cd(NH 3) 2Ni(CN),.2C 6D 6 have been measured at room temperature. Vibrational assignments are given for the bands arising from the host lattice and the guest molecules. Changes in the spectra when the samples are decomposed are also discussed.

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