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Accurate determination of the fourth stability constant of palladium(II)-halide complexes

Authors
Journal
Journal of Inorganic and Nuclear Chemistry
0022-1902
Publisher
Elsevier
Publication Date
Volume
35
Issue
2
Identifiers
DOI: 10.1016/0022-1902(73)80574-3

Abstract

Abstract Ramette's PHODEC computer program was applied to the accurate determination of the fourth stability constant of palladium-halide systems because it can make use of the calculated rather than the measured molar extinction coefficient. Comparison of the calculations based on the measured with those based on the computed values of A 0, a multiple of the molar extinction coefficient, demonstrated the greater reliability of the latter. The main source of error in the experimental determination of A 0 is probably the high ionic strength at which the measurement is performed.

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