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Synthetic approach tocisandtrans-decalins via Diels—Alder reaction and ring-closing metathesis as key steps: further extension to dioxapropellane derivative by ring-closing metathesis

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
67
Issue
2
Identifiers
DOI: 10.1016/j.tet.2010.10.080
Keywords
  • Diels–Alder Reaction
  • Ring-Closing Metathesis
  • Decalin
  • Propellane
  • Hydrogenation

Abstract

Abstract 9,10-Substituted cis and trans-decalins were synthesized by a simple route using the Diels–Alder reaction and ring-closing metathesis (RCM) as key steps. Later, the cis-decalin system has been extended to 3,8-dioxa[8.4.4]propellane derivative by RCM sequence as a key step.

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