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Total synthesis of cervinomycin A1-trimethyl ether and cervinomycin A2-methyl ether

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
32
Issue
38
Identifiers
DOI: 10.1016/s0040-4039(00)93465-8
Keywords
  • Xanthone Antibiotics
  • Photocyclisation
  • Tetrahydrooxazolo-[3
  • 2-B)Benz(G)Isoquinolone Formation.
Disciplines
  • Chemistry

Abstract

Abstract The heptacyclic framework of cervinomycin antibiotics has been constructed through a C+EFG → CEFG → CDEFG → ABCDEFG approach in which the photochemical generation of ring D was a key step.

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