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Fused Pyridine Derivatives from the Wittig Reaction of some Fluorinated Amides

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
51
Issue
37
Identifiers
DOI: 10.1016/0040-4020(95)00605-8

Abstract

Abstract Compound 2 reacted with phosphorane 3 (R = Et) giving the quinoline derivative 5 whereas thiophenes 7 and 9 gave enamines 8 and 10 respectively with the appropriate phosphorane 3 (R = Me or Et). Pyridine derivative 11 yielded only ethyl 2-aminonicotinate with phosphorane 3 (R = Et). Compounds 8 and 10 gave the fused pyridine derivatives 14 and 15 respectively when treated with sodium hydride.

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