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Ethyl-enediammonium tetraaquadi-sulfatomagnesium(II).

Authors
  • Rekik, Walid
  • Naïli, Houcine
  • Mhiri, Tahar
  • Bataille, Thierry
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
Publisher
International Union of Crystallography
Publication Date
Jan 01, 2009
Volume
65
Issue
Pt 11
Identifiers
DOI: 10.1107/S1600536809041981
PMID: 21578145
Source
Medline
License
Unknown

Abstract

The title compound, [NH(3)(CH(2))(2)NH(3)][Mg(SO(4))(2)(H(2)O)(4)], was synthesized by the slow evaporation method. Its crystal structure can be described as an alternate stacking of inorganic layers of tetra-aqua-bis(sulfato-O)magnesium [Mg(SO(4))(2)(H(2)O)(4)](2-) anions ( symmetry) and organic layers of [NH(3)(CH(2))(2)NH(3)](2+) cations along the crystallographic b axis. The anions, built up from tetrahedral SO(4) units and octahedral Mg(H(2)O)(4)O(2) units, and the cations are linked together through N-H⋯O hydrogen bonds, forming a three-dimensional network. O-H⋯O inter-actions are also present.

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