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Encapsulated reagents for nitrosation.

Authors
  • Zyryanov, Grigory V1
  • Rudkevich, Dmitry M
  • 1 Department of Chemistry & Biochemistry, University of Texas at Arlington, Arlington, Texas 76019-0065, USA.
Type
Published Article
Journal
Organic Letters
Publisher
American Chemical Society
Publication Date
Apr 17, 2003
Volume
5
Issue
8
Pages
1253–1256
Identifiers
PMID: 12688732
Source
Medline
License
Unknown

Abstract

[reaction: see text] A novel class of stable, mild, and size-shape-selective nitrosating agents for secondary amides is introduced. These are based on reversible entrapment and release of reactive nitrosonium species by calix[4]arenes. The NO(+) encapsulation controls the reaction selectivity.

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