An Enantioselective Synthesis of the ABD Tricycle for (-)-Phomactin A Featuring Rawal's Asymmetric Diels-Alder Cycloaddition.
Division of Pharmaceutical Sciences and Department of Chemistry, Rennebohm Hall, 777 Highland Avenue, University of Wisconsin, Madison, WI 53705.
- Published Article
Advanced Synthesis & Catalysis
- Publication Date
Dec 01, 2008
An enantioselective synthesis of the ABD-ring of (-)-phomactin A is described here. The sequence features Rawal's asymmetric Diels-Alder cycloaddition. The overall length is significantly reduced from our previous attempt.
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The corresponding record at NLM can be accessed at https://www.ncbi.nlm.nih.gov/pubmed/24273477