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An Enantioselective Synthesis of the ABD Tricycle for (-)-Phomactin A Featuring Rawal's Asymmetric Diels-Alder Cycloaddition.

Authors
  • You, Ling-Feng1
  • Hsung, Richard P
  • Bedermann, Aaron A
  • Kurdyumov, Aleksey V
  • Tang, Yu
  • Buchanan, Grant S
  • Cole, Kevin P
  • 1 Division of Pharmaceutical Sciences and Department of Chemistry, Rennebohm Hall, 777 Highland Avenue, University of Wisconsin, Madison, WI 53705.
Type
Published Article
Journal
Advanced Synthesis & Catalysis
Publisher
Wiley
Publication Date
Dec 01, 2008
Volume
350
Issue
18
Identifiers
DOI: 10.1002/adsc.200800552
PMID: 24273477
Source
Medline
Keywords
Language
English
License
Unknown

Abstract

An enantioselective synthesis of the ABD-ring of (-)-phomactin A is described here. The sequence features Rawal's asymmetric Diels-Alder cycloaddition. The overall length is significantly reduced from our previous attempt.

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