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Enantioselective carbonyl-ene reaction on BINOLate/titanium catalyst encapsulated in magnetic nanoreactors.

Authors
  • Liu, Xiao
  • Bai, Shiyang
  • Yang, Yan
  • Li, Bo
  • Xiao, Bing
  • Li, Can
  • Yang, Qihua
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Mar 28, 2012
Volume
48
Issue
26
Pages
3191–3193
Identifiers
DOI: 10.1039/c2cc17950d
PMID: 22331315
Source
Medline
License
Unknown

Abstract

An asymmetric multicomponent catalyst, BINOLate/titanium, successfully encapsulated in the nanocages of mesoporous silicas exhibits much higher activity than the homogeneous counterpart in quasi solvent-free enantioselective carbonyl-ene reaction, owing to the confinement effect of the nanoreactor.

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