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An enantiopure Fe(III)4 single-molecule magnet.

Authors
  • Zhu, Yuan-Yuan
  • Guo, Xiao
  • Cui, Chang
  • Wang, Bing-Wu
  • Wang, Zhe-Ming
  • Gao, Song
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Jul 27, 2011
Volume
47
Issue
28
Pages
8049–8051
Identifiers
DOI: 10.1039/c1cc12831k
PMID: 21677989
Source
Medline
License
Unknown

Abstract

A pair of enantiopure star-shaped Fe(III)(4) clusters were constructed from simple chiral ligands. AC field frequency dependence and a hysteresis loop, which are very important features of SMMs, were observed. Circular dichroism (CD) spectra demonstrated that the chirality was successfully transferred from the ligand to the coordination environment of Fe(3+) ions.

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