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En route towards alpha-benzotriazoyl nitroso derivatives

Authors
  • Monbaliu, Jean-Christophe
  • Beagle, Lucas K
  • Kovacs, Judit
  • Zeller, Matthias
  • Stevens, Christian
  • Katritzky, Alan R
Publication Date
Jan 01, 2012
Source
Ghent University Institutional Archive
Keywords
Language
English
License
Unknown
External links

Abstract

A new class of geminally-substituted nitroso compounds, i.e. alpha-benzotriazoyl nitroso derivatives, is presented. These compounds display a rather different behavior than other related nitroso compounds bearing a geminal electron-withdrawing group. An unexpected and spontaneous oxidation to the nitro analog is observed in solution.

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