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Efficient fluorinating agent through topochemical fluorination of Co-Fe layered double hydroxides.

Authors
  • Louvain, Nicolas
  • Peyroux, Jérémy
  • Dubois, Marc
  • Simond, Wikenson
  • Leroux, Fabrice
Type
Published Article
Journal
Inorganic Chemistry
Publisher
American Chemical Society
Publication Date
Jan 21, 2014
Volume
53
Issue
2
Pages
852–860
Identifiers
DOI: 10.1021/ic402193x
PMID: 24364744
Source
Medline
License
Unknown

Abstract

Mixed-metal inorganic fluoride, Co0.60Fe0.40F3, solid solutions are obtained through topochemical reactions of Co2FeCl(OH)6·2H2O LDH with molecular fluorine, F2, at temperatures as low as 100 °C. This solid solution possesses interesting F(•)-releasing ability, and its efficiency as a solid-state fluorinating agent is demonstrated on a commercial polyethylene film. (19)F solid state NMR and contact angle measurements underline the efficient fluorination of this polymer.

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