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Efficient aziridine synthesis in metastable crystalline phases by photoinduced denitrogenation of crystalline triazolines.

Authors
Type
Published Article
Journal
Organic Letters
1523-7052
Publisher
American Chemical Society
Publication Date
Volume
14
Issue
15
Pages
3874–3877
Identifiers
DOI: 10.1021/ol301582n
PMID: 22794188
Source
Medline
License
Unknown

Abstract

The solid-state photodenitrogenation of crystalline triazolines proceeds with high efficiency to form the corresponding aziridines in high chemical yields upon selection of the proper irradiation wavelength. It was shown that the solid-to-solid reactions occur by formation of the product in metastable crystalline phases.

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