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Effect of Nitrogen-Functional Groups on the ORR Activity of Activated Carbon Fiber-Polypyrrole-Based Electrodes

Authors
  • Ramírez-Pérez, Ana Cristina1
  • Quílez-Bermejo, Javier2
  • Sieben, Juan Manuel3
  • Morallón, Emilia1
  • Cazorla-Amorós, Diego2
  • 1 Universidad de Alicante, Departamento de Química Física and Instituto Universitario de Materiales, Apartado 99, Alicante, 03080, Spain , Alicante (Spain)
  • 2 Universidad de Alicante, Departamento de Química Inorgánica and Instituto Universitario de Materiales, Apartado 99, Alicante, 03080, Spain , Alicante (Spain)
  • 3 Universidad Nacional del Sur, Instituto de Ingeniería Electroquímica y Corrosión and CONICET, Av. Alem 1253, Bahía Blanca, B8000CPB, Argentina , Bahía Blanca (Argentina)
Type
Published Article
Journal
Electrocatalysis
Publisher
Springer US
Publication Date
Jul 10, 2018
Volume
9
Issue
6
Pages
697–705
Identifiers
DOI: 10.1007/s12678-018-0478-y
Source
Springer Nature
Keywords
License
Yellow

Abstract

Polypyrrole (PPy) coatings inside the microporosity of an activated carbon fiber (ACF) were synthesized by chemical polymerization obtaining ACF-PPy composites. N-doped ACFs were prepared by carbonization of the ACF-PPy composites at two temperatures (500 and 800 °C). All the samples were characterized using different techniques (XPS, SEM, elemental analysis, physical adsorption of N2, cyclic voltammetry, etc.). The electrochemical characterization in alkaline medium shows that the N-doped ACFs have a similar specific capacitance than the pristine ACF, in spite of the lower specific surface area. The materials were used as electrodes in the oxygen reduction reaction (ORR) in alkaline medium using the rotating ring-disk electrode (RRDE) and linear sweep voltammetry (LSV) tests. It was found that the N-doped ACF material carbonized at 800 °C has higher catalytic activity than the pristine ACF. The investigation also indicates that the ORR process on the N-doped ACF materials proceeds through an indirect two-electron pathway. Graphical Abstract

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