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Esca, mössbauer and infrared spectroscopic investigations of a series of tin complexes

Authors
Journal
Journal of Electron Spectroscopy and Related Phenomena
0368-2048
Publisher
Elsevier
Publication Date
Volume
40
Issue
4
Identifiers
DOI: 10.1016/0368-2048(86)80047-0
Disciplines
  • Physics

Abstract

Abstract Core electron binding shifts have been measured for a series of tin complexes. From earlier proposed relations between binding energies, infrared intensities and the charge on the ligands we have estimated the effective charge on the tin atom. Also the isomer shifts of the central atom have been measured. By using a sample model for the interpretation of these data in terms of occupation numbers of the valence orbitals, an estimate of the electronic structure of the complexes is obtained.

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