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Dimeric palladium (I) complexes containing the bridging cyclopentadienyl group

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
129
Issue
3
Identifiers
DOI: 10.1016/s0022-328x(00)92142-9

Abstract

Abstract Dimeric palladium(I) complexes of the type [μ-(η 3-C 5H 5)-μ-XPd 2(PR 3) 2](X  Br, R  i-Pr, Ph, Cy; X  Cl, I, R  i-Pr) have been prepared by reduction of the complexes [(ν 5-C 5H 5)(PR 3)PdX] with a variety of reducing agents (Mg,Na/Hg, LiAlH(t-BuO) 3, LiAlH 4, NaBH 4, n-BuMgBr). PMR and IR data and some properties of the new complexes are reported.

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