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3-Benzyl-7-methyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
65
Issue
11
Identifiers
DOI: 10.1107/s1600536809044481
Keywords
  • Organic Papers

Abstract

In the title compound, C32H32N2O2S, the pyrrolidine ring adopts a twist conformation while the tetra­hydro­pyridine ring is in a distorted half-chair conformation. The two rings are trans-fused. The dihedral angle between the sulfonyl and benzyl phenyl rings is 72.54 (14)°. The mol­ecular structure is stabilized by C—H⋯O hydrogen bonds, and N—H⋯π inter­actions involving the benzyl phenyl ring. The screw-related mol­ecules are linked into chains along the b axis by C—H⋯O hydrogen bonds and C—H⋯π inter­actions. Adjacent inversion-related chains inter­act via C—H⋯π inter­actions, forming a two-dimensional network parallel to the bc plane.

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