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Some mixed halogenomercurate(II) anionic complexes. Vibrational spectra and structure

Authors
Journal
Inorganica Chimica Acta
0020-1693
Publisher
Elsevier
Publication Date
Volume
61
Identifiers
DOI: 10.1016/s0020-1693(00)89125-2

Abstract

Abstract Anionic complexes of the type HgCl 2X − where X = Br or I have been prepared as salts of tetrapropylammonium cation. IR and Raman spectra are interpreted in terms of halogan-bridged dimeric species, in keeping with molecular weight determinations. Vibrational spectra and reactions of these complexes with 2,2′-dipyridyl allow us to infer a C 2ν(type A) structure for these species.

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