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New functional poly(N-vinylpyrrolidone) based (co)polymers via photoinitiated cobalt-mediated radical polymerization

Publication Date
  • Radical Polymerization
  • Cobalt-Mediated Radical Polymerization (Cmrp)
  • Physical
  • Chemical
  • Mathematical & Earth Sciences :: Chemistry [G01]
  • Physique
  • Chimie
  • Mathématiques & Sciences De La Terre :: Chimie [G01]
  • Engineering
  • Computing & Technology :: Materials Science & Engineering [C09]
  • Ingénierie
  • Informatique & Technologie :: Science Des Matériaux & Ingénierie [C09]


The photoinitiated cobalt-mediated radical polymerization enables the synthesis of novel alpha-functional and alpha,omega-telechelic polymers. In combination with ring-opening polymerization, it also produces new amphiphilic copolymers which self-assemble into flower-like vesicles in water.

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