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Catalytic asymmetric hydrosilylation of ketones using rhodium-(l)-complexes of chiral phosphinooxazoline ligands

Authors
Journal
Tetrahedron Asymmetry
0957-4166
Publisher
Elsevier
Publication Date
Volume
7
Issue
6
Identifiers
DOI: 10.1016/0957-4166(96)00192-9

Abstract

Hydrosilylation of aromatic and aliphatic ketones using 0.3 mol% of (phosphinooxazoline)rhodium(l) complexes as catalysis proceeds with enantioselectivities of up to 85 %. In contrast to N,N chelate ligands, no excess of phosphinooxazoline is required.

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