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Complexes of organometallic compounds:XXXIX. synthesis, infrared and mössbauer studies on monoorganotin(IV) complexes with tridentate ligands

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
78
Issue
1
Identifiers
DOI: 10.1016/s0022-328x(00)86451-7
Disciplines
  • Physics

Abstract

Abstract Novel complexes RClSntrid, where R is Me, Ph, n-Oct, and trid 2− are dianions of tridentate “planar” ligands with ONO and SNO donor atoms, were synthesized and investigated in the solid state by infrared and Mössbauer spectroscopy. Possible configurations are discussed; polymeric trigonal bipyramidal structures seem to occur, although five-coordinated monomers as well as octahedral dimers (via oxygen or sulfur bridges) are not excluded.

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