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Phase transition in melt-spun Fe88B12and Fe72B28alloys by resistivity measurements and Mössbauer spectroscopy

Authors
Journal
Solid State Communications
0038-1098
Publisher
Elsevier
Publication Date
Volume
98
Issue
5
Identifiers
DOI: 10.1016/0038-1098(96)00026-9

Abstract

Abstract Resistivity measurements and Mössbauer spectroscopy indicate that the as-quenched Fe 88B 12 and Fe 72B 28 melt-spun alloys are not completely crystallized. This is not in agreements with the earlier observations on the same alloys by DTXD measurements. In as-quenched Fe 88B 12 α-Fe, o-Fe 3B and amorphous phases are found while in Fe 72B 28 the phases found are α-Fe and t-Fe 3B. The phases o-Fe 3B and t-Fe 3B are metastable while t-Fe 2B is stable upto 825K.

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