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Stabilization of organosilver(I) compounds, and their application in organic synthesis

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
172
Issue
3
Identifiers
DOI: 10.1016/s0022-328x(00)92371-4
Disciplines
  • Chemistry

Abstract

Abstract The favourable influence of lithium bromide on the thermal stability of organosilver(I) compounds is described. The stabilized silver(I) compounds have been brought into reaction with conjugated enynes; the regiochemistry of the reactions appears to depend on steric factors. A comparison is presented of the behaviour of the silver(I) and the corresponding copper(I) reagents in this reaction.

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