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Regiocontrolled synthesis of bicyclo[3.2.1]octane derivatives by cuprate addition and intramolecular acylation

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
21
Issue
40
Identifiers
DOI: 10.1016/0040-4039(80)80220-6

Abstract

Abstract Copper-catalysed reaction of 4-butenylmagnesium bromide with cyclohexenones (2) and (5) occurs with intramolecular acylation of the intermediate enolate to give bicyclo[3.2.1]octane derivatives (4) and (6).

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