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Konsekutive umlagerungen eines 2-azabicyclo[2.2.2]octen-derivates in das 1-azatricyclo[3.2.1.O2,7]- und das 6-azabicyclo[3.2.1]octan-system

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
27
Issue
5
Identifiers
DOI: 10.1016/s0040-4039(00)84040-x

Abstract

Abstract In contrast to similar ring system the O-tosyl derivative 2 is rearranged exclusively to the tricyclic aziridine 4. Further tosylation produces the bicyclic tosyl amide 5. The corresponding O-benzoyl-derivatives 6 rearrange in the usual manner with π-assistence to give 7.

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