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Intramolecular michael addition reaction to chiral vinylic sulfoxides. An enantioselective synthesis of (R)- and (S)-1,7-dioxaspiro[5.5]undecane

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
26
Issue
18
Identifiers
DOI: 10.1016/s0040-4039(00)98967-6

Abstract

Abstract (R)- and (S)-1,7-Dioxaspiro[5.5]undecane ((R)- 1 and (S)- 1), sex pheromone of an olive fly, was each stereoselectively synthesized using an intramolecular Michael addition of hydroxyl group to a chiral vinylic sulfoxide moiety as an asymmetric induction step.

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