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catena-Poly[bis­(μ3-2-methyl-3,5-dinitro­benzoato)disilver(I)]

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
67
Issue
7
Identifiers
DOI: 10.1107/s1600536811022483
Source
Legacy
Keywords
  • Metal-Organic Papers

Abstract

In the title coordination polymer, [Ag2(C8H5N2O6)2]n, the silver ion is coordinated to three O atoms from three different anions in an approximate T-shape with one bond much longer than the other two. The polyhedral connectivity leads to [100] chains containing alternating centrosymmetric four-rings and eight-rings, with a short d 10⋯d 10 Ag⋯Ag interaction [2.8846 (4) Å] across the latter. The nitro groups are oriented at dihedral angles of 21.2 (5) and 64.3 (3)° with respect to the aromatic ring of the ligand. A C—H⋯O inter­action occurs in the crystal.

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