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Photochemical synthesis of the tungsten(II) complex [WCl2(CO)3(bipy)]

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
375
Issue
1
Identifiers
DOI: 10.1016/0022-328x(89)85087-9
Disciplines
  • Chemistry

Abstract

Abstract The photochemical oxidationn of W(CO) 6 to [W(CO) 4Cl 2] 2 withCCl 4 has been used to give [WCl 2(CO) 3(bipy)]. The same methodology was applied in the synthesis W(II) complexes having the nitrogen ligands acetonitrile, N,N,N′,N′-tetramethylethylenediamine, pyridine, 1,10-phenathroline, 2,9-dimethyl-1,10-phenathroline, and to make the Mo II and Cr II complexes [MCl 2(CO) 3(bipy)] (M = Mo, Cr).

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