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Highly regioselective iodoperfluoroalkylation of allenes with perfluoroalkyl iodides upon irradiation with near-UV light

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
42
Issue
13
Identifiers
DOI: 10.1016/s0040-4039(01)00207-6

Abstract

Abstract Upon irradiation through Pyrex with a xenon lamp ( hν>300 nm), perfluoroalkyl iodides add to terminal allenes regioselectively to afford the corresponding iodoperfluoroalkylated products, where perfluoroalkyl and iodo groups are selectively introduced into the terminal and central carbons of allenes, respectively.

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