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Pentaorganyle des antimons

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
17
Issue
3
Identifiers
DOI: 10.1016/s0022-328x(00)88225-x
Disciplines
  • Chemistry

Abstract

Abstract Some new spirocycles of pentacoordinated antimony are described. By means of the temperature-dependent proton-resonance spectra of the antimony penta- organyls (XXXV) and (XXXVI) conclusions concerning the dynamic stereochemistry of these derivatives are possible. The cyclic stibines, essential for the synthesis of the pentavalent antimony derivatives, are prepared by a new method with the aid of bidentate cadmium organyls.

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