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3.20 Stoichiometric Auxiliary Ligands for Metals and Main Group Elements: Ligands for Lithium

Authors
Publisher
Elsevier Ltd
Identifiers
DOI: 10.1016/b978-0-08-095167-6.00320-7
Keywords
  • Chiral Auxiliary
  • Chiral Ligand
  • Lithium Amide
  • Organolithium Compound

Abstract

Abstract Chiral ligands for lithium were classified into two types: those connecting to reactants through a covalent bond and those connecting to the reactants without a covalent bond. These ligands were believed to dissociate oligomeric organolithium compounds in solution and activate them toward electrophiles and acidic compounds in an asymmetric environment. This chapter describes not only reactions with stoichiometric ligands but also catalytic reactions.

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