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Synthesis and resolution of a new P-chiral hydroxy phosphine

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
603
Issue
2
Identifiers
DOI: 10.1016/s0022-328x(00)00190-x
Keywords
  • Hydroxyphosphines
  • P-Chiral
  • Metallacycles
  • Resolution
  • Palladium

Abstract

Abstract The synthesis of the functionalized P-chiral phosphine BzPhP{CH(OH)Ph}and its resolution by palladium metallacycles is reported. The cyclopalladated compound containing the primary amine 1-(1-naphthyl)ethylamine has been shown to be a better resolving agent for this phosphine than the corresponding metallacycle containing the tertiary amine N, N-dimethyl-1-(1-naphthyl)ethylamine

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