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Activation parameters for the reaction of phenylchloro carbene with pyridine, tri-n-butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefins

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
30
Issue
11
Identifiers
DOI: 10.1016/s0040-4039(00)99458-9

Abstract

Abstract The activation energies for reaction of phenylchloro carbene with pyridine, tri-n-butyl-tin hydride and triethylsilane are reported. The data argues against reversibly formed complexes in the reaction of this carbene with olefins.

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