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Ruthenium-catalyzed regioselective α-alkylation of ketones with primary alcohols

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
43
Issue
44
Identifiers
DOI: 10.1016/s0040-4039(02)01625-8
Keywords
  • Alkylation
  • Ketones
  • Primary Alcohols
  • Ruthenium Catalyst

Abstract

Abstract Ketones are regioselectively alkylated with an array of primary alcohols in dioxane at 80°C in the presence of a catalytic amount of a ruthenium catalyst together with KOH and a hydrogen acceptor.

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