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Infrared multiphoton dissociation of CF3Br

Authors
Journal
Chemical Physics
0301-0104
Publisher
Elsevier
Publication Date
Volume
35
Issue
3
Identifiers
DOI: 10.1016/s0301-0104(78)85247-1
Disciplines
  • Physics

Abstract

Abstract The CF 2, Br, and F products of 9.2 μ multiphoton dissociation of CF 3Br have been spectroscopically monitored. Primary dissociation leads to CF 3 + Br, while secondary dissociation of CF 3 leads to CF 2 + F. Both the Br and F atoms are found to have average recoil energies close to those of thermal (300 K) atoms. Comparison of these results to calculations based on RRKM theory indicates that CF 3Br dissociates from levels 2–5 photons above the CF 3 + Br threshold.

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