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Importance de la conformation des complexes XC6H5Cr(CO)3pour la regiosélectivité d'additions nucleophiles sur le cycle aromatique

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
21
Issue
32
Identifiers
DOI: 10.1016/s0040-4039(00)77403-x

Abstract

Abstract The site of preferred nucleophilic attack on XC 6H 5Cr(CO) 3 complexes is more influenced by the conformation of the Cr(CO) 3 group than by the nature of X substituent. This is supported both by experimental and theoretical results.

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