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Directing the reactivity of [HFe4N(CO)12]- toward H+ or CO2 reduction by understanding the electrocatalytic mechanism.

Authors
Type
Published Article
Journal
Journal of the American Chemical Society
1520-5126
Publisher
American Chemical Society
Publication Date
Volume
133
Issue
46
Pages
18577–18579
Identifiers
DOI: 10.1021/ja208312t
PMID: 22032761
Source
Medline
License
Unknown

Abstract

Selective reactivity of an electrocatalytically generated catalyst-hydride intermediate toward the hydrogen evolution reaction (HER) or reduction of CO(2) is key for a CO(2) reduction electrocatalyst. Under appropriate conditions, Et(4)N[Fe(4)N(CO)(12)] (Et(4)N-1) is a catalyst for the HER or for CO(2) conversion at -1.25 V vs SCE using a glassy carbon electrode.

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