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Direct dehydrative cross-coupling of tautomerizable heterocycles with alkynes via Pd/Cu-catalyzed phosphonium coupling.

Authors
  • Kang, Fu-An
  • Lanter, James C
  • Cai, Chaozhong
  • Sui, Zhihua
  • Murray, William V
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Feb 28, 2010
Volume
46
Issue
8
Pages
1347–1349
Identifiers
DOI: 10.1039/b917777a
PMID: 20449299
Source
Medline
License
Unknown

Abstract

The first chemoselective direct dehydrative cross-coupling of tautomerizable heterocycles with alkynes has been achieved via C-H/C-OH bond activations with direct C(sp(2))-C(sp) bond formation, which is in line with ideal synthesis using readily available materials.

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