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Diazido-bis[2,4-diamino-6-(2-pyrid-yl)-1,3,5-triazine-κN,N]zinc(II).

Authors
  • Zhao, Qi-Hua
  • Fan, Ai-Ling
  • Li, Li-Nan
  • Xie, Ming-Jing
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
Publisher
International Union of Crystallography
Publication Date
Jan 01, 2009
Volume
65
Issue
Pt 6
Identifiers
DOI: 10.1107/S1600536809016055
PMID: 21582992
Source
Medline
License
Unknown

Abstract

In the title mononuclear complex, [Zn(N(3))(2)(C(8)H(8)N(6))(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa-hedral environment by four N atoms from two 2,4-diamino-6-(2-pyrid-yl)-1,3,5-triazine ligands and two N atoms from two end-on-coordinated azide ions. N-H⋯N hydrogen bonds between the ligand and azide ion link the complex mol-ecules into a three-dimensional network.

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